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DC Field | Value | Language |
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dc.contributor.author | Carmona Vargas, Christian C. | - |
dc.contributor.author | Aristizábal, Sandra L. | - |
dc.contributor.author | Belalcázar, María I. | - |
dc.contributor.author | D'Vries, Richard F. | - |
dc.contributor.author | Chaur, Manuel N. | - |
dc.date.accessioned | 2020-02-09T22:15:39Z | - |
dc.date.available | 2020-02-09T22:15:39Z | - |
dc.date.issued | 2018-12-13 | - |
dc.identifier.issn | 00201693 | - |
dc.identifier.uri | https://repository.usc.edu.co/handle/20.500.12421/2653 | - |
dc.description.abstract | Herein, we determined the binding constants for transition metal complexes of Cu2+, Co2+, Fe2+, Ni2+, and Zn2+ ions formed with the ligand picolinaldehyde-2-pyridylhydrazone (PapyH) using the Benesi-Hildebrand method. Stoichiometry 2:1 (ligand: metal) was previously determined by the Job’s method and confirmed by single-crystal X-ray diffraction finding a propeller-like structure of the [Fe(Papy)2] compound. PapyH and the metal complexes were characterized by 1H NMR and UV-Vis spectroscopy, respectively. The Cu2+ complex exhibited the highest stability constant, which was confirmed by competitive reaction of different metal ions with the ligand PapyH. | es |
dc.language.iso | en | es |
dc.publisher | Elsevier S.A. | es |
dc.subject | Binding constants | es |
dc.subject | Benesi-Hildebrand method | es |
dc.subject | Hydrazones | es |
dc.subject | Job's method | es |
dc.subject | Metal complexes | es |
dc.title | Determination of the binding constants of propeller-like metal complexes of picolinaldehyde-2-pyridylhydrazone | es |
dc.type | Article | es |
Appears in Collections: | Artículos Científicos |
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Determination of the binding constants of propeller-like metal.jpg | 135.94 kB | JPEG | View/Open |
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