Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/20.500.12421/2742
Title: Photochemical and Electrochemical Triggered Bis(hydrazone) Switch
Authors: Gordillo, Mónica A.
Soto Monsalve, Mónica
Carmona Vargas, Christian C.
Gutiérrez, Gustavo
D'vries, Richard F.
Lehn, Jean Marie
Chau, Manuel N.
Keywords: Bis(hydrazone)
Configurational isomers
Photoisomerization
Supramolecular chemistry
Thiopyrimidine
Issue Date: 17-Aug-2017
Publisher: Wiley-VCH Verlag
Abstract: Herein, we report the synthesis of a double hydrazone capable of undergoing photochemical E/Z isomerization through the imine double bonds. The bis(hydrazone) 1‐E,E can be considered as a “two‐arm” system in which the controlled movement of each arm is obtained by photo‐modulation, making possible the appearance of two isolable metastable isomeric states 1‐E,Z and 1‐Z,Z. Such states are characterized by very specific structural, optical, and electrochemical properties. The latter allows the reversible return from either 1‐E,Z or 1‐Z,Z to the 1‐E,E state. Our results are of great importance in the further development of molecular machines and photochemically controlled reactions by introducing for the first time double hydrazones as tunable photochemical switches.
URI: https://repository.usc.edu.co/handle/20.500.12421/2742
ISSN: 09476539
Appears in Collections:Artículos Científicos

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