Please use this identifier to cite or link to this item: http://localhost:8080/xmlui/handle/20.500.12421/4534
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dc.contributor.authorVillada, Juan D.-
dc.contributor.authorCarmona Vargas, Christian C.-
dc.contributor.authorAlcides Ellena, Javier-
dc.contributor.authorAyala, Alejandro P.-
dc.contributor.authorRamírez Pradilla, Juan S.-
dc.contributor.authorCombariza, M. Y.-
dc.contributor.authorGalarza, Esperanza-
dc.contributor.authorD'Vries, Richard Fernando-
dc.contributor.authorChaur, Manuel N.-
dc.date.accessioned2020-10-23T22:57:39Z-
dc.date.available2020-10-23T22:57:39Z-
dc.date.issued2020-08-25-
dc.identifier.issn0022-4596-
dc.identifier.urihttp://repository.usc.edu.co/handle/20.500.12421/4534-
dc.description.abstractHerein we report the synthesis and structural characterization of a new Ni-bis(hydrazone) complex with the chemical formula [Ni2(L)2(Cl)2](Cl)2·2H2O (L ​= ​2-(heptylthio)-4,6-bis(2-((E)-pyridin-2-ylmethylene)hydrazineyl)pyrimidine). Suitable crystals for X-ray diffraction showed the supramolecular interactions of this complex to exhibit a helical structure coordinating two Ni2+ metal ions bounded by two 2-(heptylthio)-4,6-bis(2-((E)-pyridin-2-ylmethylene)hydrazineyl)pyrimidine ligands. In addition, exploitation of the electrochemical properties by cyclic voltammetry, for this helicate, showed catalyzing ability for the reduction of H+ to H2.en_US
dc.language.isoenen_US
dc.publisherAcademic Press Inc.en_US
dc.subjectBis(hydrazones)en_US
dc.subjectCatalyzed hydrogen reductionen_US
dc.subjectNickel helicatesen_US
dc.subjectSupramolecular chemistryen_US
dc.titleSynthesis, characterization, and redox potential properties of a new double-stranded Ni-bis(hydrazone)-based helicateen_US
dc.typeArticleen_US
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