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dc.contributor.authorGordillo, Mónica A.-
dc.contributor.authorSoto-Monsalve, Mónica-
dc.contributor.authorCarmona-Vargas, Christian C.-
dc.contributor.authorGutierrez, Gustavo-
dc.contributor.authorD'vries, Richard F.-
dc.contributor.authorLehn, Jean-Marie-
dc.contributor.authorChaur, Manuel N.-
dc.date.accessioned2019-08-05T23:01:06Z-
dc.date.available2019-08-05T23:01:06Z-
dc.date.issued2017-
dc.identifier.issn1521-3765-
dc.identifier.urihttps://repository.usc.edu.co/handle/20.500.12421/482-
dc.description.abstractHerein, we report the synthesis of a double hydrazone capable of undergoing photochemical E/Z isomerization through the imine double bonds. The bis(hydrazone) 1-E,E can be considered as a ""two-arm"" system in which the controlled movement of each arm is obtained by photo-modulation, making possible the appearance of two isolable metastable isomeric states 1-E,Z and 1-Z,Z. Such states are characterized by very specific structural, optical and electrochemical properties. The latter, allows the reversible return from either 1-E,Z or 1-Z,Z to the 1-E,E state. Our results are of great importance in the further development of molecular machines and photochemically controlled reactions by introducing for the first time double hydrazones as tunable photochemical switches.en_US
dc.language.isoenen_US
dc.publisherChemistry - A European Journalen_US
dc.subjectBis(hydrazone)en_US
dc.subjectconfigurational isomersen_US
dc.subjectphotoisomerizationen_US
dc.subjectsupramolecular chemistryen_US
dc.subjectthiopyrimidineen_US
dc.titleA Photochemical and Electrochemical Triggered Bis(hydrazone) Switchen_US
dc.typeArticleen_US
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